Anomers can be interconverted through a process known as mutarotation.
2.
Mutarotation is considerably slower at temperatures close to.
3.
Typically, the anomeric carbon undergoes mutarotation in solution, and the result is an equilibrium mixture of alpha-beta configurations.
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One can monitor the mutarotation process over time or determine the equilibrium mixture by observing the optical rotation and how it changes.
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Mutarotation was discovered by Dubrunfaut in 1846, when he noticed that the specific rotation of aqueous sugar solution changes with time.
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Mutarotation was discovered by French chemist Dubrunfaut in 1846, when he noticed that the specific rotation of aqueous sugar solution changes with time.
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Mutarotation consists of a temporary reversal of the ring-forming reaction, resulting in the open-chain form, followed by a reforming of the ring.
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The third step is the formation of Neu5Ac initially as the ?-anomer, and then mutarotation and release as the more thermodynamically-stable ?-Neu5Ac.
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The molecule can change between these two forms by a process called mutarotation, that consists in a reversal of the ring-forming reaction followed by another ring formation.
10.
Over time, some of the ?-D-glucopyranose will undergo mutarotation to become ?-D-glucopyranose, which has an optical rotation of + 112.2.
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