It was marketed by Bayer under the brand name "'Salophen "'as an analgesic in the late 19th and early 20th centuries.
2.
In these compounds tetradentate Schiff-base phenoxide ( salophen ) and ?-diketonate ligands are bound along the equatorial plane, which stabilizes the U V species obtained by the single electron reduction of U VI species.
3.
The expression " inherently chiral " was first used by Boehmer to describe calixarenes with XXYZ or WXYZ substitution patterns at the upper rim, and has been later extended to fullerenes with a chiral molecular framework, like C76, C78, and C84, non symmetric uranyl-salophen complexes and the protonated Schiff base of 11-cis-retinal, the chromophore of rhodopsin.
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